The symbol of the exclamation mark in an open book is referring you to your owner’s manual.
I always go through the manual when I get a new car. Admittedly, it’s not the most exciting read, but apart from information on the basics such as fuel and tyre pressures, it helps me familiarise myself with the various features / functions of the car from day-one, reducing the chance that I might discover a ‘new’ feature 2-3 years into ownership that I could’ve been making use of.
The fuel filler flap sticker shows petrol that has a minimum octane rating of 95 RON is fine to use. From the owner’s manual under ‘Petrol’ section;
Petrol types
Vehicles with a petrol engine must run on unleaded petrol in compliance with the European standard EN 228 ⇒ . Fuels with a maximum ethanol content of 10% (E10) can be used for refuelling.
Petrol types are categorised according to their octane number, e.g. 91, 95 or 98 RON (RON = research octane number). The vehicle may be filled with petrol that has a higher octane number than the engine requires. However, this does not provide any advantage in terms of fuel consumption or engine output. Where petrol complying with the EN 228 standard is not available, Volkswagen dealerships will have information on which fuels are suitable for the vehicle. Volkswagen recommends using petrol with a low sulphur content or sulphur-free petrol for petrol engines.
And from the manual under the ‘Tyre Pressure’ section;

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Information on the tyre pressure sticker⇒ Fig. 167 :
A - Specified pressure for the tyres on the front axle.
B - Specified pressure for the tyres on the rear axle.
1 - Tyre pressure for cold tyres.
2 - Tyre pressure for partial load.
3 - In some vehicles: comfort tyre pressure for partial load.
4 - Tyre pressure for full load.
5 - Tyre pressure level for the spare or temporary spare wheel.
Comfort tyre pressure
In some vehicles the tyre pressure sticker may show details of a "comfort" tyre pressure ⇒ Fig. 167③ . This should make driving extra comfortable. Fuel consumption may increase when driving with comfort tyre pressure.
If any of the above items don’t appear on your sticker, then they’re not relevant to your Polo model.